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dc.contributor.authorDemirbaş, Ümit
dc.contributor.authorÖzçifçi, Zehra
dc.contributor.authorAkçay, Hakkı Türker
dc.contributor.authorMenteşe, Emre
dc.date.accessioned2020-12-19T19:34:44Z
dc.date.available2020-12-19T19:34:44Z
dc.date.issued2020
dc.identifier.citationDemirbaş, Ü., Özçiftçi, Z., Akçay, H.T. & Menteşe, E. (2020). Novel phthalocyanines bearing 1,2,4 triazole substituents: Synthesis, characterization, photophysical and photochemical properties. Polyhedron, 181, 114470. https://doi.org/10.1016/j.poly.2020.114470en_US
dc.identifier.issn0277-5387
dc.identifier.urihttps://doi.org/10.1016/j.poly.2020.114470
dc.identifier.urihttps://hdl.handle.net/11436/1157
dc.descriptionOZCIFCI, ZEHRA/0000-0001-8218-7136; AKCAY, Hakki Turker/0000-0002-8502-9608en_US
dc.descriptionWOS: 000523765800007en_US
dc.description.abstract4-(4,5-Diphenyl-4H-1,2,4-triazol-3-ylthio)phthalonitrile ( 3) and its non-peripherally tetra substituted zinc(II) phthalocyanine (4) and magnesium(II) phthalocyanine (5) derivatives were prepared. the novel compounds 3-5 were characterized spectroscopically. To determine the photodynamic therapy potential of 4 and 5, their photophysical and photochemical properties were investigated. the magnesium(II) phthalocyanine (5) showed the highest fluorescence quantum yield. in addition, non-peripheral substitution of the 4-(4,5-diphenyl-4H-1,2,4-triazol-3-ylthio) groups on the phthalocyanine ring did not affect the fluorescence properties of the phthalocyanines. the zinc(II) phthalocyanine (4) exhibited the highest singlet oxygen quantum yield value. the 4 and 5 exhibited lower photostability than Std-ZnPc. These results show that the zinc(II) phthalocyanine (4) can be used in photodynamic therapy applications with its singlet oxygen production and photostability. (C) 2020 Elsevier Ltd. All rights reserved.en_US
dc.language.isoengen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPhthalocyanineen_US
dc.subjectTriazoleen_US
dc.subjectFluorescenceen_US
dc.subjectSinglet oxygenen_US
dc.subjectPhotostabilityen_US
dc.subjectPhotosensitizeren_US
dc.titleNovel phthalocyanines bearing 1,2,4 triazole substituents: Synthesis, characterization, photophysical and photochemical propertiesen_US
dc.typearticleen_US
dc.contributor.departmentRTEÜ, Fen - Edebiyat Fakültesi, Kimya Bölümüen_US
dc.contributor.institutionauthorÖzçifçi, Zehra
dc.contributor.institutionauthorAkçay, Hakkı Türker
dc.contributor.institutionauthorMenteşe, Emre
dc.identifier.doi10.1016/j.poly.2020.114470
dc.identifier.volume181en_US
dc.relation.journalPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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