Exploring options for the application of azobenzene for molecular solar thermal energy storage: integration with parabolic trough solar systems

Abstract

Molecular solar thermal (MOST) energy systems can be utilized for the absorption, storage, and release of energy from the ultraviolet (UV) band of the solar spectrum. In this study, we designed a molecular solar thermal energy storage and release device based on the photoisomerization reaction of azobenzene. The device was integrated with a parabolic trough solar system, broadening the absorption range of the solar spectrum. By utilizing a coated secondary reflector, the system achieved efficient reflection of ultraviolet (UV) light in the 290–490 nm range, while solid-state azobenzene enabled the conversion of photon energy into chemical energy for storage and release. Experimental results under winter outdoor conditions demonstrated that: the secondary reflector significantly enhanced UV light concentration; the molecular solar thermal energy device exhibited remarkable thermal efficiency. Under an average solar irradiance of 302.23 W·m−2, the device demonstrated excellent thermal performance, with the azobenzene reaching a peak temperature of 42.07 °C. The maximum heat release capacity was measured at 10.89 kJ·kg−1·m−1, while achieving a remarkable heat release power of 29.31 W·kg−1·m−1.