dc.contributor.author | Demir, Selçuk | |
dc.contributor.author | Çepni, Hamide Merve | |
dc.contributor.author | Holynska, Malgorzata | |
dc.contributor.author | Kavanoz, Muammer | |
dc.contributor.author | Yılmaz, Fatih | |
dc.contributor.author | Zorlu, Yunus | |
dc.date.accessioned | 2020-12-19T19:49:11Z | |
dc.date.available | 2020-12-19T19:49:11Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | Demri, S., Cepni, H.M., Holynska, M., Kavanoz, M., Yılmaz, F. & Zorlu, Y. (2017). Copper(II) complexes with pyridine-2,6-dicarboxylic acid from the oxidation of copper(I) iodide. Journal of Coordination Chemistry, 70(19), 3422-3433. https://doi.org/10.1080/00958972.2017.1393071 | en_US |
dc.identifier.issn | 0095-8972 | |
dc.identifier.issn | 1029-0389 | |
dc.identifier.uri | https://doi.org/10.1080/00958972.2017.1393071 | |
dc.identifier.uri | https://hdl.handle.net/11436/2236 | |
dc.description | Demir, Selcuk/0000-0002-5719-7145; Zorlu, Yunus/0000-0003-2811-1872; YILMAZ, Fatih/0000-0002-7711-0975 | en_US |
dc.description | WOS: 000417651300010 | en_US |
dc.description.abstract | Via an oxidation reaction of Cu(I) iodide with pyridine-2,6-dicarboxylic acid (H2L) in DMF three copper(II) complexes, [(CH3)(2)NH2](2)[CuL2] (1), K-2 [CuL2]center dot H2L center dot H2O(2) and [Cu(L)(H2O)](n) (3), were synthesized and characterized. the structures of 1-3 were determined by single crystal X-ray diffraction studies. In-situ DMF decomposition produces dimethylamine base under solvothermal conditions and a proton transfer reaction takes place for the complex formation of 1. 3-D networks are stabilized in 1 and 2 via hydrogen bonds. Complex 3 is a 1-D coordination polymer with Cu-O semi-coordination bonds. Thermal decomposition of the complexes results in the corresponding metal oxides. Also, the electrochemical behavior of 1 was determined to be a metal-centered and diffusion-controlled, one-electron reduction process. [GRAPHICS] . | en_US |
dc.description.sponsorship | Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [112T956] | en_US |
dc.description.sponsorship | This work was supported by the Scientific and Technological Research Council of Turkey (TUBITAK) [Grant number 112T956]. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Taylor & Francis Ltd | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Copper | en_US |
dc.subject | Pyridine-2,6-dicarboxylic acid | en_US |
dc.subject | Proton transfer | en_US |
dc.subject | Dipicolinic acid | en_US |
dc.subject | Cyclic voltammetry | en_US |
dc.title | Copper(II) complexes with pyridine-2,6-dicarboxylic acid from the oxidation of copper(I) iodide | en_US |
dc.type | article | en_US |
dc.contributor.department | RTEÜ, Fen - Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.contributor.institutionauthor | Demir, Selçuk | |
dc.contributor.institutionauthor | Çepni, Hamide Merve | |
dc.contributor.institutionauthor | Kavanoz, Muammer | |
dc.contributor.institutionauthor | Yılmaz, Fatih | |
dc.identifier.doi | 10.1080/00958972.2017.1393071 | |
dc.identifier.volume | 70 | en_US |
dc.identifier.issue | 19 | en_US |
dc.identifier.startpage | 3422 | en_US |
dc.identifier.endpage | 3433 | en_US |
dc.relation.journal | Journal of Coordination Chemistry | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |