dc.contributor.author | Karaoğlu, Kaan | |
dc.contributor.author | Baran, Talat | |
dc.contributor.author | Değirmencioğlu, İsmail | |
dc.contributor.author | Serbest, Kerim | |
dc.date.accessioned | 2020-12-19T20:10:55Z | |
dc.date.available | 2020-12-19T20:10:55Z | |
dc.date.issued | 2011 | |
dc.identifier.citation | Karaoğlu, K., Baran, T., Değirmencioğlu, I., & Serbest, K. (2011). Synthesis and spectroscopic studies of homo-binuclear, alkoxo bridged homo- and hetero-tetranuclear metal complexes of a bis-N2O4 Schiff base ligand derived from ethanolamine and macroacyclic tetranaphthaldehyde. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 79(5), 867–872. https://doi.org/10.1016/j.saa.2011.03.015 | en_US |
dc.identifier.issn | 1386-1425 | |
dc.identifier.uri | https://doi.org/10.1016/j.saa.2011.03.015 | |
dc.identifier.uri | https://hdl.handle.net/11436/3616 | |
dc.description | PubMed: 21550297 | en_US |
dc.description.abstract | Three new homo-binuclear Ni(II), Cu(II), Zn(II) complexes (2-4), homo-tetranuclear Cu(II) complex (5), and hetero-tetranuclear Cu(II)-Ni(II) complex (6) of a macroacyclic potentially bis-hexadentate N 2O 4 Schiff base have been synthesized. The imino-alcohol ligand, H 4L was obtained by the condensation of ethanolamine with 2,2?-[2,3-bis(1-formyl-2-naphthyloxymethyl)-but-2-ene-1,4-diyldioxy] bis(naphthalene-1-carbaldehyde). The structures of both the Schiff base and its complexes have been proposed by elemental analyses, spectroscopic data i.e. IR, 1H and 13C NMR, UV-vis, electrospray ionisation mass spectra, molar conductivities and magnetic susceptibility measurements. The ligand has two similar compartments to bind first primary two metal ions, and acts bi- or tetra-negative, bis-tetradentate forming five membered chelate ring. However, secondary two metal ions (either Cu 2+ or Ni 2+) are ligated with dianionic oxygen atoms of the alcohol groups and are linked to the 1,10-phenanthroline-nitrogen atoms in the tetranuclear complexes (5 and 6). © 2011 Elsevier B.V. All rights reserved. | en_US |
dc.description.sponsorship | 107T383 Türkiye Bilimsel ve Teknolojik Araştirma Kurumu | en_US |
dc.description.sponsorship | The authors thank The Scientific and Technological Research Council of Turkey (TUBITAK) for financial support (Project Number: 107T383). | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Elsevier | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Binucleating | en_US |
dc.subject | Characterization | en_US |
dc.subject | Polynuclear complex | en_US |
dc.subject | Schiff bases | en_US |
dc.subject | Synthesis | en_US |
dc.title | Synthesis and spectroscopic studies of homo-binuclear, alkoxo bridged homo- and hetero-tetranuclear metal complexes of a bis-N 2O 4 Schiff base ligand derived from ethanolamine and macroacyclic tetranaphthaldehyde | en_US |
dc.type | article | en_US |
dc.contributor.department | RTEÜ, Fen - Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.contributor.institutionauthor | Karaoğlu, Kaan | |
dc.contributor.institutionauthor | Baran, Talat | |
dc.contributor.institutionauthor | Serbest, Kerim | |
dc.identifier.doi | 10.1016/j.saa.2011.03.015 | |
dc.identifier.volume | 79 | en_US |
dc.identifier.issue | 5 | en_US |
dc.identifier.startpage | 867 | en_US |
dc.identifier.endpage | 872 | en_US |
dc.relation.journal | Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |