dc.contributor.author | Demirbaş, Ümit | |
dc.contributor.author | Yanık, Hülya | |
dc.contributor.author | Akçay, Hakkı Türker | |
dc.contributor.author | Durmuş, Mahmut | |
dc.contributor.author | Bekircan, Olcay | |
dc.contributor.author | Kantekin, Halit | |
dc.date.accessioned | 2022-11-14T13:28:15Z | |
dc.date.available | 2022-11-14T13:28:15Z | |
dc.date.issued | 2022 | en_US |
dc.identifier.citation | Demirbas, U., Yanik, H., Akcay, H.t., Durmus, m., Bekircan, O. & Kantekin, H. (2022). Synthesis, characterization, photophysical and photochemical properties of peripherally tetra-1,2,4-triazol-3-ylthio substituted metal-free phthalocyanine and its zinc(II) and lead(II) derivatives. Journal of Coordination Chemistry , 75(3-4), 448-456. https://doi.org/10.1080/00958972.2022.2053846 | en_US |
dc.identifier.issn | 0095-8972 | |
dc.identifier.issn | 1029-0389 | |
dc.identifier.uri | https://doi.org/10.1080/00958972.2022.2053846 | |
dc.identifier.uri | https://hdl.handle.net/11436/7029 | |
dc.description.abstract | Phthalonitrile (3) including 4-(4-fluorophenyl)-5-(4-methoxyphenyl)-4H-1,2,4-triazole-3-thio substituent and its peripherally tetra substituted metal-free (4), zinc(II) (5) and lead(II) (6) phthalocyanine derivatives were prepared and characterized by FTIR, mass, H-1-NMR and C-13-NMR spectroscopic data. All studied phthalocyanines had good solubility in common organic solvents and did not aggregate. The photophysical and photochemical behaviors of the phthalocyanine complexes (4-6) were examined in DMSO to determinate their PDT potential. Singlet oxygen, fluorescence and photodegradation quantum yields showed that zinc(II) phthalocyanine (5) has potential as Type II photosensitizer for PDT applications. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Taylor & Francis Ltd. | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Triazole | en_US |
dc.subject | Phthalocyanine | en_US |
dc.subject | Singlet oxygen | en_US |
dc.subject | Fluorescence quenching | en_US |
dc.subject | Photosensitizer | en_US |
dc.title | Synthesis, characterization, photophysical and photochemical properties of peripherally tetra-1,2,4-triazol-3-ylthio substituted metal-free phthalocyanine and its zinc(II) and lead(II) derivatives | en_US |
dc.type | article | en_US |
dc.contributor.department | RTEÜ, Fen - Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.contributor.institutionauthor | Akçay, Hakkı Türker | |
dc.identifier.doi | 10.1080/00958972.2022.2053846 | en_US |
dc.identifier.volume | 75 | en_US |
dc.identifier.issue | 3-4 | en_US |
dc.identifier.startpage | 448 | en_US |
dc.identifier.endpage | 456 | en_US |
dc.relation.journal | Journal of Coordination Chemistry | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |