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Synthesis of unsymmetrical 3,5-disubstituted 1,2,4-triazole derivatives with their pKa values
(Chiminform Data S A, 2014)
Acylhydrazones (2a-b) were synthesized by the condensation of iminoester hydrochlorides (1a-b) with benzhydrazide. the treatment of acylhydrazones With hydrazine hydrate afforded 4-amino-4H-1,2,4-triazoles. (3a-b). ...