dc.contributor.author | Baran, Talat | |
dc.contributor.author | Karaoğlu, Kaan | |
dc.contributor.author | Serbest, Kerim | |
dc.contributor.author | Ağır, Hülya | |
dc.contributor.author | Sandallı, Cemal | |
dc.contributor.author | Değirmencioğlu, İsmail | |
dc.date.accessioned | 2020-12-19T20:04:17Z | |
dc.date.available | 2020-12-19T20:04:17Z | |
dc.date.issued | 2013 | |
dc.identifier.citation | Baran, T., Karaoglu, K., Serbest, K., Agir, H. Sandalli, C., Degirmencioglu, I. (2013). Studies on synthesis, structure, and DNA cleaving of homo-dinuclear Mn(II), Cu(II), Ni(II), and Zn(II) complexes with a heterocycle-based macroacyclic Schiff base. Monatshefte Fur Chemie, 144(8), 1107-1115. https://doi.org/10.1007/s00706-013-0926-6 | en_US |
dc.identifier.issn | 0026-9247 | |
dc.identifier.issn | 1434-4475 | |
dc.identifier.uri | https://doi.org/10.1007/s00706-013-0926-6 | |
dc.identifier.uri | https://hdl.handle.net/11436/3306 | |
dc.description | KARAOGLU, Kaan/0000-0003-3265-8328; KARAOGLU, Kaan/0000-0003-3265-8328; BARAN, TALAT/0000-0003-0206-3841; SANDALLI, Cemal/0000-0002-1298-3687 | en_US |
dc.description | WOS: 000321920800003 | en_US |
dc.description.abstract | (E,E',E'',E''')-N,N',N'',N'''-[(1,2-ethenyliden)tetrakis[methylenoxy(2,1-naphthalinediyl)methylidyne]tetrakis[1,2,4-triazol-4-amine] and its novel homo-dinuclear Mn(II), Ni(II), Cu(II), and Zn(II) complexes have been synthesized and characterized by elemental analyses, spectroscopic data (i.e., IR, H-1 and C-13 NMR, UV-Vis), electrospray ionisation mass spectra, XRD, DSC, molar conductivity, and magnetic susceptibility measurements. the absorption bands observed in the electronic spectra and magnetic moment values confirm an octahedral environment around the metal ion. the molar conductivity measurements confirm the non-ionic character of these complexes. the DNA cleavage activities of the Schiff base and its homo-dinuclear complexes are also investigated. Results suggest that all the complexes used can be evaluated as nuclease mimics. | en_US |
dc.description.sponsorship | Scientific and Technological Research Council of TURKEY (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [107T383] | en_US |
dc.description.sponsorship | The authors thank the Scientific and Technological Research Council of TURKEY (TUBITAK) for financial support (Project Number: 107T383). | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Springer Wien | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Coordination chemistry | en_US |
dc.subject | Heterocycles | en_US |
dc.subject | Schiff bases | en_US |
dc.subject | Binucleating | en_US |
dc.subject | DNA cleaving | en_US |
dc.title | Studies on synthesis, structure, and DNA cleaving of homo-dinuclear Mn(II), Cu(II), Ni(II), and Zn(II) complexes with a heterocycle-based macroacyclic Schiff base | en_US |
dc.type | article | en_US |
dc.contributor.department | RTEÜ, Teknik Bilimler Meslek Yüksekokulu, Kimya ve Kimyasal İşleme Teknolojileri Bölümü | en_US |
dc.contributor.institutionauthor | Karaoğlu, Kaan | |
dc.contributor.institutionauthor | Değirmencioğlu, İsmail | |
dc.contributor.institutionauthor | Ağır, Hülya | |
dc.contributor.institutionauthor | Serbest, Kerim | |
dc.identifier.doi | 10.1007/s00706-013-0926-6 | |
dc.identifier.volume | 144 | en_US |
dc.identifier.issue | 8 | en_US |
dc.identifier.startpage | 1107 | en_US |
dc.identifier.endpage | 1115 | en_US |
dc.relation.journal | Monatshefte Fur Chemie | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |