dc.contributor.author | Demir, Selçuk | |
dc.contributor.author | Yılmaz, Veysel T. | |
dc.contributor.author | Sarıboğa, Bahtiyar | |
dc.contributor.author | Büyükgüngör, Orhan | |
dc.contributor.author | Mrozinski, Jerzy | |
dc.date.accessioned | 2020-12-19T20:11:41Z | |
dc.date.available | 2020-12-19T20:11:41Z | |
dc.date.issued | 2010 | |
dc.identifier.citation | Demir, S., Yılmaz, V.T., Sarıboğa, B., Büyükgüngör, O. & Mrozinski, J. (2010). Metal(II) nicotinamide complexes containing succinato, succinate and succinic acid: Synthesis, crystal structures, magnetic, thermal, antimicrobial and fluorescent properties. Journal of Inorganic and Organometallic Polymers and Materials, 20(2), 220-278. https://doi.org/10.1007/s10904-010-9340-2 | en_US |
dc.identifier.issn | 1574-1443 | |
dc.identifier.uri | https://doi.org/10.1007/s10904-010-9340-2 | |
dc.identifier.uri | https://hdl.handle.net/11436/3770 | |
dc.description.abstract | Four novel divalent transitional metal succinates (suc) with nicotinamide (nia), {[M(?-suc)(H 2O) 2(nia) 2]·2H 2O} n [M = Mn (1), Ni (2)], [Cu(suc)(nia) 2] (3) and [Ni(H 2O) 4(nia) 2](suc)·(H 2suc) (4), have been synthesized and characterized by elemental analyses, IR and TG-DTA. X-ray analyses of 2 and 4 reveal that they crystallize in a triclinic space group, Complex 2 is a 1-D coordination polymer, in which the metal(II) ions exhibit an octahedral geometry with two suc, two nia and two aqua ligands. The nia ligand is N-bonded, while the suc ligand bridges the metal centres through the carboxylate groups. 4 contains the [Ni(H 2O) 4(nia) 2] 2+ complex cations, uncoordinated suc and H 2suc species, which are connected into a two-dimensional layered structure by the combination of N-H...O and OW-H...O hydrogen bonds. This is one of the scarce examples encountered in coordination chemistry, which contains uncoordinated suc and H 2suc at the same time. The spectroscopic and structural analysis, luminescent and magnetic properties and the antimicrobial activities of the synthesized complexes were investigated. © 2010 Springer Science+Business Media, LLC. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Springer Link | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Antimicrobial activity | en_US |
dc.subject | Crystal structure | en_US |
dc.subject | Magnetic properties | en_US |
dc.subject | Nicotinamide | en_US |
dc.subject | Succinate complexes | en_US |
dc.subject | Thermal analysis | en_US |
dc.title | Metal(II) nicotinamide complexes containing succinato, succinate and succinic acid: Synthesis, crystal structures, magnetic, thermal, antimicrobial and fluorescent properties | en_US |
dc.type | article | en_US |
dc.contributor.department | RTEÜ, Fen - Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.contributor.institutionauthor | Demir, Selçuk | |
dc.identifier.doi | 10.1007/s10904-010-9340-2 | |
dc.identifier.volume | 20 | en_US |
dc.identifier.issue | 2 | en_US |
dc.identifier.startpage | 220 | en_US |
dc.identifier.endpage | 228 | en_US |
dc.relation.journal | Journal of Inorganic and Organometallic Polymers and Materials | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |