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dc.contributor.authorSerbest, K.
dc.contributor.authorKayi, H.
dc.contributor.authorEr, M.
dc.contributor.authorSancak, K.
dc.contributor.authorDeğirmencioğlu, I.
dc.date.accessioned2020-12-19T20:12:36Z
dc.date.available2020-12-19T20:12:36Z
dc.date.issued2008
dc.identifier.issn1042-7163
dc.identifier.urihttps://doi.org/10.1002/hc.20496
dc.identifier.urihttps://hdl.handle.net/11436/3905
dc.description.abstractFour new mononuclear metal complexes with a mononucleating Schiff base ligand containing two thiadiazoles units have been synthesized. The ligand and metal complexes were characterized by elemental analyses, IR, 1H, and 13C NMR, UV-vis, ESR, electrospray ionization mass spectra, and magnetic susceptibility measurements. Electronic spectra, magnetic susceptibility measurement, and molecular modeling studies support octahedral geometry around the Ni(II), Cu(II), and Zn(II) ions. The magnetic properties were investigated, and ferromagnetic coupling is observed in Cu(II) and Ni(II) complexes. In addition, total energy and heat of formation calculated for conformers of the Schiff base ligand by the semiempirical AM1 calculations have shown that E,Z-isomer of the ligand is more stable (about 5.3 kcal/mol) than E,E- and Z,Z-isomers. © 2008 Wiley Periodicals, Inc.en_US
dc.language.isoengen_US
dc.publisher0-Belirleneceken_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleNi(II), Cu(II), and Zn(II) complexes of tetradentate schiff base containing two thiadiazoles units: Structural, spectroscopic, magnetic properties, and molecular modeling studiesen_US
dc.typearticleen_US
dc.contributor.departmentRTEÜen_US
dc.identifier.doi10.1002/hc.20496
dc.identifier.volume19en_US
dc.identifier.issue7en_US
dc.identifier.startpage700en_US
dc.identifier.endpage712en_US
dc.relation.journalHeteroatom Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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