Yazar "Karaoğlu, Kaan" için FEF, Kimya Bölümü Koleksiyonu listeleme
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Acetate bridged dinuclear Cu(II) complexes with ferrocene based benzimidazol ligands: Synthesis, spectroscopy, electrochemistry, DFT calculations and catecholase activity
Karaoğlu, Kaan; Emirik, Mustafa; Menteşe, Emre; Zengin, Ali; Serbest, Kerim (Pergamon-Elsevier Science Ltd, 2016)Two new benzimidazole ligands, 1-[(E)-ferrocenylmethylidenehydrazino]-2-{5,6-dichloro-2-[(o-chloro-phenyl)methyl]-1,3-diaza-1H-inden-1-yl}-1-ethanone (1) and 1-[(E)-ferrocenylmethylidenehydrazino]-2-{2-[p-(trifluoromethy ... -
Catalytic activity of palladium doped activated carbon from waste coffee on some environmental pollutants
Karaoğlu, Kaan; Özçifçi, Zehra; Çalışkan, Melike; Baran, Talat; Akçay, Hakkı Türker (Elsevier, 2022)The presence of nitro compounds and such commercial dyes as Congo red, methylene blue, methyl orange and methyl red in water/wastewater causes environmental issues. The treatment of such industrial contaminants, new efficient ... -
Detection of Fe2+ in acetonitrile/water mixture by new 8-hydroxyquinolin based sensor through metal displacement mechanism
Karaoğlu, Kaan; Akçay, Hakkı Türker; Yılmaz, İsmail (Elsevier Science Bv, 2017)A 8-hydroxyquinoline-based (8-HQ) fluorescent ligand (2) was designed and synthesized by condensation of pyridine-2-carboxaldehide with 2-(quinolin-8-yloxy)acetohydrazide (1). Fluorometric titrations with various metal ... -
Experimental and computational studies on 4-[(3,5-dimethyl-1H-pyrazol-1-yl) methoxy]phthalonitrile and synthesis and spectroscopic characterization of its novel phthalocyanine magnesium(ii) and tin(ii) metal complexes
Akçay, Hakkı Türker; Bayrak, Rıza; Şahin, Ertan; Karaoğlu, Kaan; Demirbaş, Ümit (Elsevier B.V., 2013)The molecular structure of the substituted phthalonitrile was analyzed crystallographically and compared with optimized geometric structure. The structural properties of the compound such as energy, vibrational frequency, ... -
Ferrocenyl-substituted dinuclear Cu(II) complex: Synthesis, spectroscopy, electrochemistry, DFT calculations and catecholase activity
Emirik, Mustafa; Karaoğlu, Kaan; Serbest, Kerim; Menteşe, Emre; Yılmaz, İsmail (Elsevier Science Bv, 2016)A new ferrocenyl-substituted heterocyclic hydrazide ligand and its Cu(II) complex were prepared. the DFT calculations were performed to determine the electronic and molecular structures of the title compounds. the electronic ... -
Mesoporous chromium oxide doped palladium catalysis for cyanation reaction of some aryl halides
Karaoğlu, Kaan; Akçay, Hakkı Türker; Özçifçi, Zehra; Çalışkan, Melike; Baran, Talat (Elsevier, 2021)A Pd/Cr2O3 hybrid catalyst for cyanation reaction of some aryl halides was synthesized and characterized by XRD, SEM/EDS and TEM. The porous structure of the catalyst was also investigated by BET analysis. All XRD ... -
Mononuclear Cu(II) complex of an oxime ligand derived from N-Heterocyclic hydrazide: Synthesis, spectroscopy, electrochemistry, DFT calculations and catecholase activity
Zengin, Ali; Karaoğlu, Kaan; Emirik, Mustafa; Menteşe, Emre; Serbest, Kerim (Elsevier Science Bv, 2019)A new oxime derivative N-heterocyclic hydrazide ligand, N'-[(1E,2E)-2-(hydroxyimino)-1-methylpropylidene]-2-[(4-methyl-5-phenyl-4H-1,2,4-triazol-3-1)thio] acetohydrazide (1) and its mono-nuclear copper(II) complex (1a) ... -
A new activated carbon-supported Pd-ZnO catalyst for Heck Cross-coupling reactions
Karaoğlu, Kaan; Özçifçi, Zehra; Çalışkan, Melike; Akçay, Hakkı Türker; Baran, Talat (Elsevier, 2023)In this work, to develop catalysts for Heck-type coupling reactions, a hybrid ZnO-Pd nanocatalyst was fabricated on activated carbon sourced from polymer debris. Such techniques as transmission electron microscopy (TEM), ... -
A new fluorescent "turn-off" coumarin-based chemosensor: Synthesis, structure and Cu-selective fluorescent sensing in water samples
Karaoğlu, Kaan; Yılmaz, Fatih; Menteşe, Emre (Springer/Plenum Publishers, 2017)We report the synthesis and characterization two coumarin-based fluorescence probes, N'-{[7-(diethylamino)-2-oxo-2H-chromen-3-yl]carbonyl}pyridine-3-carbohydrazide (3) and N'-benzoyl-7-(diethylamino)-2-oxo-2H-chromene-3- ... -
Occurrence of microplastics in herpetological museum collection: Grass snake (Natrix natrix [Linnaeus, 1758]) and dice anake (Natrix tessellata [Laurenti, 1769]) as model organisms
Gül, Serkan; Karaoğlu, Kaan; Özçifçi, Zehra; Candan, Kamil; Ilgaz, Çetin; Kumlutaş, Yusuf (Springer, 2022)Microplastics are plastic fragments with a size less than 5 mm in length. In addition to a threat to the marine environments where these are abundantly present, these have also started polluting freshwater ecosystems. ... -
Oxime derivative unsymmetrical azine, its Ni(II), Cu(II) and Zn(II) complexes: Synthesis, spectroscopy and catecholase activity
Serbest, Kerim; Göktekin, Özge; Karaoğlu, Kaan; Zengin, Ali; Coruh, Ufuk (Wiley-Hindawi, 2018)1-[(Z)-{(2E)-[(3E)-3-(hydroxyimino)butan-lidene]hydrazinylidene}methyl]naphthalen -2-ol, H2L (3) was synthesized by the agents of 2-hydroxy-1-naphtaldehyde, 2,3-butanedione monoxime and hydrazine in two steps. the structures ... -
Preparation and characterization of the highly efficient tetraphenylimidazole substituted Phthalocyanine/ZnO composite and investigation of its effect on the photocatalytic degradation of Rhodamine B and 2,4,6-trichlorophenol
Karaoğlu, Kaan; Yüzüak, Gizem Durak; Yüzüak, Ercüment; Turan, Hanife; Akçay, Hakkı Türker (Elsevier, 2024)Growing concerns about industrial waste-induced environmental degradation have driven research towards sustainable solutions. Photocatalytic degradation, fueled by light and avoiding harmful chemicals, offers a promising ... -
Spectroscopic, electrochemical, theoretical characterization and biological evaluation of a ferrocenyl-substituted unsymmetric azine ligand and its Cu(II) complex
Özel, Arzu; Karaoğlu, Kaan; Serbest, Kerim; Gürcan, Nihan; Emirik, Mustafa; Coruh, Ufuk (Taylor & Francis Ltd, 2016)Ferrocenyl-substituted unsymmetrical azine and its Cu(II) complex were prepared. the redox active ferrocene-based azine was obtained by condensation of 1-[(E)-hydrazono]-5-bromo-2-hydroxybenzene with ferrocene carboxaldehyde. ... -
Synthesis and spectroscopic studies of homo-binuclear, alkoxo bridged homo- and hetero-tetranuclear metal complexes of a bis-N 2O 4 Schiff base ligand derived from ethanolamine and macroacyclic tetranaphthaldehyde
Karaoğlu, Kaan; Baran, Talat; Değirmencioğlu, İsmail; Serbest, Kerim (Elsevier, 2011)Three new homo-binuclear Ni(II), Cu(II), Zn(II) complexes (2-4), homo-tetranuclear Cu(II) complex (5), and hetero-tetranuclear Cu(II)-Ni(II) complex (6) of a macroacyclic potentially bis-hexadentate N 2O 4 Schiff base have ... -
Synthesis, characterization and properties of tetra((l-hydroxyimino- methylnaphthalen-2-yloxy)methyl)etheneandits homo-dinuclear metal complexes: A combined experimental and theoretical investigation
Serbest, Kerim; Karaoğlu, Kaan; Erman, Murat; Er, Mustafa; Değirmencioğlu, İsmail (Elsevier B.V., 2010)Tetra((l-hydroxyiminomethylnaphthalen-2-yloxy)methyl)ethene (THlMNYOME), H4L, was synthesized by the agents of 2-hydroxy-l -naphtaldehyde, tetra(bromomethyl)ethene and hydroxylamine hydrochloride in two steps. Characterization ... -
Synthesis, characterization, spectral and electrical properties of peripherally tetratriazole-substituted phthalocyanines and its metal complexes
Bayrak, Rıza; Karaoğlu, Kaan; Ünver, Yasemin; Sancak, Kemal; Dumludağ, Fatih; Değirmencioğlu, İsmail (Elsevier, 2012)The substituted [1,2,4]triazole 3 was obtained from the reaction between compound 1 and compound 2. Novel substituted phthalonitrile 5 was prepared by the substitution of the nitro group of 4-nitrophthalonitrile 4 with ... -
An unsymmetrical ferrocene based azine and its Cu(II) complex: Spectroscopy, crystal structure, electrochemistry and DFT calculations
Karaoğlu, Kaan; Serbest, Kerim; Emirik, Mustafa; Şahin, Ertan (Elsevier Science Sa, 2015)An unsymmetrical ferrocenyl-substituted azine ligand and its Cu(II) complex have been prepared in this study. the redox active ferrocene-based azine ligand was obtained by condensation of 2-methanehydrazonoylphenol and ...