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dc.contributor.authorAkyüz, Duygu
dc.contributor.authorDemirbaş, Ümit
dc.contributor.authorAkçay, Hakkı Türker
dc.date.accessioned2020-12-19T19:32:23Z
dc.date.available2020-12-19T19:32:23Z
dc.date.issued2020
dc.identifier.citationAkyüz, D., Demirbaş, Ü. & Akçay, H.T. (2020). Synthesis, characterization and electrochemistry of 1-phenoxypropan-2-yloxy substituted phthalocyanines. Journal of Organometallic Chemistry, 923, 121455. https://doi.org/10.1016/j.jorganchem.2020.121455en_US
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2020.121455
dc.identifier.urihttps://hdl.handle.net/11436/1007
dc.descriptionAKCAY, Hakki Turker/0000-0002-8502-9608en_US
dc.descriptionWOS: 000575167700012en_US
dc.description.abstract4-(1-phenoxypropan-2-yloxy)phthalonitrile (3) and peripherally tetra 1-phenoxypropan-2-yloxy substituted zinc(II) (4), cobalt(II) (5) and copper(II) (6) phthalocyanine were prepared. Structural characterization of novel complexes was performed by spectrophotometric measurements. the determination of the redox active or redox inactive metal center effect on the electrochemistry, in-situ spectroelectrochemisty and electrocolorimetry of compounds were performed in dimethylformamide. the redox properties and mechanisms were examined by electrochemical measurements. the peripherally tetra substituted cobalt(II) phthalocyanine (5) showed both metal and ligand-based redox processes, while zinc(II) (4) and cobalt(II) phthalocyanines only displayed ligand-based redox processes. These results were confirmed by electrochemical and in-situ spectroelectrochemical measurements. Moreover, the semiconducting nature of the compounds were illuminated via electrochemical measurements. (C) 2020 Elsevier B.V. All rights reserved.en_US
dc.language.isoengen_US
dc.publisherElsevier Science Saen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPhthalonitrileen_US
dc.subjectPhthalocyanineen_US
dc.subjectElectrochemistryen_US
dc.subjectSpectroelectrochemistryen_US
dc.subjectElectrocolorimetryen_US
dc.titleSynthesis, characterization and electrochemistry of 1-phenoxypropan-2-yloxy substituted phthalocyaninesen_US
dc.typearticleen_US
dc.contributor.departmentRTEÜ, Fen - Edebiyat Fakültesi, Kimya Bölümüen_US
dc.contributor.institutionauthorAkçay, Hakkı Türker
dc.identifier.doi10.1016/j.jorganchem.2020.121455
dc.identifier.volume923en_US
dc.relation.journalJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US


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