dc.contributor.author | Özel, Arzu | |
dc.contributor.author | Karaoğlu, Kaan | |
dc.contributor.author | Serbest, Kerim | |
dc.contributor.author | Gürcan, Nihan | |
dc.contributor.author | Emirik, Mustafa | |
dc.contributor.author | Coruh, Ufuk | |
dc.date.accessioned | 2020-12-19T19:56:04Z | |
dc.date.available | 2020-12-19T19:56:04Z | |
dc.date.issued | 2016 | |
dc.identifier.citation | Ozel, A., Karaoglu, k., Serbest, K., Gurcan, N., Emirik, M., Coruh, U. (2016). Spectroscopic, electrochemical, theoretical characterization and biological evaluation of a ferrocenyl-substituted unsymmetric azine ligand and its Cu(II) complex. Journal of Coordination Chemistry, 69(10), 1587-1601. https://doi.org/10.1080/00958972.2016.1178387 | en_US |
dc.identifier.issn | 0095-8972 | |
dc.identifier.issn | 1029-0389 | |
dc.identifier.uri | https://doi.org/10.1080/00958972.2016.1178387 | |
dc.identifier.uri | https://hdl.handle.net/11436/2666 | |
dc.description | KARAOGLU, Kaan/0000-0003-3265-8328; KARAOGLU, Kaan/0000-0003-3265-8328; Hokelek, Tuncer/0000-0002-8602-4382; emirik, mustafa/0000-0001-9489-9093 | en_US |
dc.description | WOS: 000377773300005 | en_US |
dc.description.abstract | Ferrocenyl-substituted unsymmetrical azine and its Cu(II) complex were prepared. the redox active ferrocene-based azine was obtained by condensation of 1-[(E)-hydrazono]-5-bromo-2-hydroxybenzene with ferrocene carboxaldehyde. the ferrocenyl ligand and its Cu(II) complex were characterized by IR, UV-vis, NMR, X-ray, magnetic susceptibility, molar electrical conductivity measurements, and TG techniques. the redox behaviors of the ferrocene compounds were investigated by cyclic voltammetry. Structural parameters and spectroscopic properties of the ligand and the Cu(II) complex were calculated by employing density functional theory (DFT) and time-dependent DFT and compared with available experimental data. We found slightly stronger binding ability for Cu(II) complex than the free ligand. DNA binding abilities for ferrocenyl-substituted unsymmetrical azine ligand and its Cu(II) complex are higher than some reported ferrocene compounds. We also studied DNA cleavage, superoxide and DPPH radical scavenging abilities of the compounds. Furthermore, the synthesized organometallic compounds can be bound to DNA through an intercalative mode. [GRAPHICS] . | en_US |
dc.description.sponsorship | Research Fund of Recep Tayyip Erdogan UniversityRecep Tayyip Erdogan University [2011.102.02.1]; Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [114Z059] | en_US |
dc.description.sponsorship | This work was supported by the Research Fund of Recep Tayyip Erdogan University [grant number 2011.102.02.1] (Rize/Turkey); Scientific and Technological Research Council of Turkey (TUBITAK) [grant number 114Z059]. the numerical calculations reported in this paper were performed at TUBITAK ULAKBIM, High Performance and Grid Computing Center (TRUBA Resources). | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Taylor & Francis Ltd | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Ferrocene | en_US |
dc.subject | DNA interaction | en_US |
dc.subject | Antioxidant activity | en_US |
dc.subject | Crystal structure | en_US |
dc.subject | DFT calculations | en_US |
dc.title | Spectroscopic, electrochemical, theoretical characterization and biological evaluation of a ferrocenyl-substituted unsymmetric azine ligand and its Cu(II) complex | en_US |
dc.type | article | en_US |
dc.contributor.department | RTEÜ, Fen - Edebiyat Fakültesi, Kimya Bölümü | en_US |
dc.contributor.institutionauthor | Karaoğlu, Kaan | |
dc.contributor.institutionauthor | Emirik, Mustafa | |
dc.identifier.doi | 10.1080/00958972.2016.1178387 | |
dc.identifier.volume | 69 | en_US |
dc.identifier.issue | 10 | en_US |
dc.identifier.startpage | 1587 | en_US |
dc.identifier.endpage | 1601 | en_US |
dc.relation.journal | Journal of Coordination Chemistry | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |