| dc.contributor.author | Günay, Güneş | |
| dc.contributor.author | Yeşilel, Okan Zafer | |
| dc.contributor.author | Erer, Hakan | |
| dc.contributor.author | Keskin, Seda | |
| dc.contributor.author | Tabak, Ahmet | |
| dc.date.accessioned | 2020-12-19T19:56:26Z | |
| dc.date.available | 2020-12-19T19:56:26Z | |
| dc.date.issued | 2015 | |
| dc.identifier.citation | Gunay, G., Yesilel, O.Z., Erer, H., Keskin, S., Tabak, A. (2015). A zinc(II) metal organic framework based on flexible o-phenylenediacetate and rigid 4,4 '-azobis(pyridine) ligands: Synthesis, crystal structure and hydrogen gas adsorption property. Polyhedron, 100, 108-113. https://doi.org/10.1016/j.poly.2015.07.017 | en_US |
| dc.identifier.issn | 0277-5387 | |
| dc.identifier.uri | https://doi.org/10.1016/j.poly.2015.07.017 | |
| dc.identifier.uri | https://hdl.handle.net/11436/2732 | |
| dc.description | keskin, seda/0000-0001-5968-0336; YESILEL, Okan Zafer/0000-0002-2284-1578; Erer, Hakan/0000-0003-3540-8797 | en_US |
| dc.description | WOS: 000365363100014 | en_US |
| dc.description.abstract | A new three-dimensional (3D) metal organic framework, [Zn-2(mu(4)-o-pda)(2)(mu-abpy)](n) (1), has been synthesized by the hydrothermal reaction and characterized by FT-IR spectroscopy, elemental analysis, thermal analysis, X-ray powder diffraction, and single crystal X-ray diffraction techniques (o-H(2)pda = o-phenylenediacetic acid and abpy = 4,4'-azobis(pyridine)). Single crystal X-ray diffraction study reveals that complex 1 exhibits a binodal (3,7)-connected three-dimensional framework (3D) with the point symbol of (3.5(2))(3(2).4(4).5(7).6(7).7). Thermal analysis reveal that complex 1 is stable up to 300 degrees C. in order to investigate the potential of 1 in gas storage applications, we performed experiments and atomically detailed simulations to obtain H-2 adsorption isotherm at a pressure range of 0-1 atm at 77 K. (C) 2015 Elsevier Ltd. All rights reserved. | en_US |
| dc.description.sponsorship | Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [1649B031402373]; Scientific Research Fund of Eskisehir Osmangazi UniversityEskisehir Osmangazi University [201519029] | en_US |
| dc.description.sponsorship | This work has been supported by the Scientific and Technological Research Council of Turkey (TUBITAK, No: 1649B031402373) and the Scientific Research Fund of Eskisehir Osmangazi University (Project number: 201519029). | en_US |
| dc.language.iso | eng | en_US |
| dc.publisher | Pergamon-Elsevier Science Ltd | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | o-Phenylenediacetate | en_US |
| dc.subject | 4.4 '-Azobis(pyridine) | en_US |
| dc.subject | Zinc(II) complex | en_US |
| dc.subject | Coordination polymer | en_US |
| dc.subject | Metal organic framework | en_US |
| dc.title | A zinc(II) metal organic framework based on flexible o-phenylenediacetate and rigid 4,4 '-azobis(pyridine) ligands: Synthesis, crystal structure and hydrogen gas adsorption property | en_US |
| dc.type | article | en_US |
| dc.contributor.department | RTEÜ, Fen - Edebiyat Fakültesi, Kimya Bölümü | en_US |
| dc.contributor.institutionauthor | Tabak, Ahmet | |
| dc.identifier.doi | 10.1016/j.poly.2015.07.017 | |
| dc.identifier.volume | 100 | en_US |
| dc.identifier.startpage | 108 | en_US |
| dc.identifier.endpage | 113 | en_US |
| dc.relation.journal | Polyhedron | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
